The hydrochemistry of a semi-arid pan basin case study: Sua Pan,Makgadikgadi, Botswana     

Frank D. Eckardt  Robert G. Bryant  Graham McCulloch  Baruch Spiro  Warren W. Wood 《Applied Geochemistry》2008

This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m³ of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (⁸⁷Sr/⁸⁶Sr average 0.722087) and S (δ³⁴S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.  相似文献   

The soilmodels.info project   总被引：1，自引：0，他引：1  

Gerd Gudehus  Angelo Amorosi  Antonio Gens  Ivo Herle  Dimitrios Kolymbas  David Mašín  David Muir Wood  Andrzej Niemunis  Roberto Nova  Manuel Pastor  Claudio Tamagnini  Gioacchino Viggiani 《国际地质力学数值与分析法杂志》2008,32(12):1571-1572

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Research challenges at the land–sea interface     

Drew M. Talley  Elizabeth W. North  Andrew R. Juhl  David A. Timothy  Daniel Conde  Jody F. C. deBrouwer  Cheryl A. Brown  Linda M. Campbell  Tobias Garstecki  Catherine J. Hall  Filip J. R. Meysman  David M. Nemerson  Pedro W. Souza Filho  Robert J. Wood 《Estuarine, Coastal and Shelf Science》2003,58(4):699

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Microcoleus autumnalis and filamentous algae-dominated mats and chlorophyll-a increase with agricultural land use but respond differently to associated nutrient and sediment enrichment     

Susanna A. Wood  Annika Wagenhoff  Logan Brown  Javier Atalah 《新西兰海洋与淡水研究杂志》2020,54(3):449-466

ABSTRACT

This study investigated the impact of pastoral land use and nutrient and fine sediment inputs on Microcoleus autumnalis and filamentous algae-dominated mats, and benthic chlorophyll-a in streams (lower North Island, New Zealand). Surveying and sampling was undertaken monthly at 61 sites spanning a wide gradient in catchment cover and environmental conditions. Two boosted regression tree models were built. The first models included pastoral land cover and five environmental variables as predictors. In the second model pastoral land cover was replaced by nutrient/sediment data. The abundance of the two mat types and chlorophyll-a increased when pastoral land cover was between 20% and 70% (model 1). Replacement of pastoral land cover by nutrient/sediment data (model 2) slightly improved the model fit for all three periphyton variables. Microcoleus autumnalis-dominant mats increased with dissolved inorganic nitrogen concentrations up to ca. 0.6?mg?L^?1, and in streams with more frequent flushes. In contrast, filamentous algal-dominated mats increased with turbidity, and in streams with less frequent flushes. Chlorophyll-a generally followed the response of the dominant periphyton type. Increased knowledge on responses of specific periphyton types, rather than total biomass, to environmental variables is essential to guide effective management strategies.  相似文献   

Changing grading of soil: effect on critical states   总被引：6，自引：3，他引：3  

David Muir Wood  Kenichi Maeda 《Acta Geotechnica》2008,3(1):3-14

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.  相似文献   

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions   总被引：5，自引：0，他引：5  

P. Pan  S. A. Wood 《Mineralium Deposita》1994,29(5):373-390

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.  相似文献   

Boulder 1, Station 2, Apollo 17: Petrology and petrogenesis     

Graham Ryder  Douglas B. Stoeser  Ursula B. Marvin  Janice F. Bower  John A. Wood 《Earth, Moon, and Planets》1975,14(3-4):327-357

Boulder 1, Station 2, Apollo 17 is a stratified boulder containing dark clasts and dark-rimmed light clasts set in a light-gray friable matrix. The gray to black clasts (GCBx and BCBx) are multigenerational, competent, high-grade metamorphic, and partially melted breccias. They contain a diverse suite of lithic clasts which are mainly ANT varieties, but include granites, basaltic-textured olivine basalts, troctolitic and spinel troctolitic basalts, and unusual lithologies such as KREEP norite, ilmenite (KREEP) microgabbro, and the Civet Cat norite, which is believed to be a plutonic differentiate. The GCBxs and BCBxs are variable in composition, averaging a moderately KREEPy olivine norite. The matrix consists of mineral fragments derived from the observed lithologies plus variable amounts of a component, unobserved as a clast-type, that approximates a KREEP basalt in composition, as well as mineral fragments of unknown derivation. The high-temperature GCBxs cooled substantially before their incorporation into the friable matrix of Boulder 1. The light friable matrix (LFBx) is texturally distinct from the competent breccia clasts and, apart from the abundant ANT clasts, contains clasts of a KREEPy basalt that is not observed in the competent breccias. The LFBx lacks such lithologies as the granites and the Civet Cat norite observed in the competent breccias and in detail is a distinct chemical as well as textural entity. We interpret the LFBx matrix as Serenitatis ejecta deposited in the South Massif, and the GCBx clasts as remnants of an ejecta blanket produced by an earlier impact. The source terrain for the Serenitatis impact consisted of the competent breccias, crustal ANT lithologies, and the KREEPy basalts, attesting to substantial lunar activity prior to the impact. The age of the older breccias suggests that the Serenitatis event is younger than 4.01±0.03 b.y.  相似文献   

Moving Geochemical Transactions forward as an open access journal     

Martin AA Schoonen  Ken B Anderson  Scott A Wood 《Geochemical transactions》2006,7(1):1-2

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Thermal expansion and crystal structure of FeSi between 4 and 1173 K determined by time-of-flight neutron powder diffraction     

L. Vočadlo  K. S. Knight  G. D. Price  I. G. Wood 《Physics and Chemistry of Minerals》2002,29(2):132-139

The thermal expansion and crystal structure of FeSi has been determined by neutron powder diffraction between 4 and 1173?K. No evidence was seen of any structural or magnetic transitions at low temperatures. The average volumetric thermal expansion coefficient above room temperature was found to be 4.85(5)?×?10^?5?K^?1. The cell volume was fitted over the complete temperature range using Grüneisen approximations to the zero pressure equation of state, with the internal energy calculated via a Debye model; a Grüneisen second-order approximation gave the following parameters: θ_D=445(11)?K, V ₀=89.596(8)?ų, K ₀′=4.4(4) and γ′=2.33(3), where θ_D is the Debye temperature, V ₀ is V at T=0?K, K ₀′ is the first derivative with respect to pressure of the incompressibility and γ′ is a Grüneisen parameter. The thermodynamic Grüneisen parameter, γ_th, has been calculated from experimental data in the range 4–400?K. The crystal structure was found to be almost invariant with temperature. The thermal vibrations of the Fe atoms are almost isotropic at all temperatures; those of the Si atoms become more anisotropic as the temperature increases.  相似文献   

Erratum to Shinichi Sakane, Wenbin Liu, Douglas J. Doren, Everett L. Shock, and Robert H. Wood (2001) prediction of the Gibbs energies and an improved equation of state for water at extreme conditions from Ab Initio energies with classical simulations, Geochimica et Cosmochimica Acta65, 4067-4075     

Robert H Wood 《Geochimica et cosmochimica acta》2002,66(24):4365

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